A molecular photovoltaic system based on Dawson type polyoxometalate and porphyrin formed by layer-by-layer self assembly

Iftikhar Ahmed; Rana Farha; Michel Goldmann; Laurent Ruhlmann

doi:10.1039/C2CC37519B

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Chemical Communications

Issue 5, 2013

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A molecular photovoltaic system based on Dawson type polyoxometalate and porphyrin formed by layer-by-layer self assembly

Iftikhar Ahmed,^a Rana Farha,^b^c Michel Goldmann^b^c and Laurent Ruhlmann*^a^d

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Laboratoire de Chimie Physique (UMR CNRS 8000), Bâtiment 349, Université de Paris-Sud 11, F - 91405 Orsay cedex, France

INSP, UMR 7588 CNRS-UPMC, 4 Place Jussieu, 75252 Paris, France

Laboratoire d'Analyse et Contrôle des Systèmes Complexes - LACSC-ECE Paris Ecole d'Ingénieurs, 37 Quai de Grenelle, F - 75015 Paris, France

Laboratoire d'Electrochimie et de Chimie-Physique du Corps Solide (UMR CNRS 7177), Université de Strasbourg, 4 rue Blaise Pascal, 67081 Strasbourg, France
E-mail: lruhlmann@unistra.fr

Chem. Commun., 2013,49, 496-498

DOI: 10.1039/C2CC37519B
Received 15 Oct 2012, Accepted 20 Nov 2012
First published online 20 Nov 2012

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Films based on electrostatic interactions between tetracationic porphyrin and Dawson type polyoxometalate are formed by the so called layer-by-layer method. Their photovoltaic performances are investigated by photocurrent transient measurements which showed significant photocurrent response.

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