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Issue 2, 2013
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A quick access to the spirotricyclic core analogue of mangicol A by a Rh(I)-catalyzed tandem Pauson–Khand/[4+2] cycloaddition

Wei Chen,ab  Jia-Hui Tay,b  Jun Ying,b  Michal Sabat,b  Xiao-Qi Yu*a  and  Lin Pu*b 
Author affiliations

* Corresponding authors

a Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, China

b Department of Chemistry, University of Virginia, Charlottesville, USA
E-mail: lp6n@virginia.edu, xqyu@scu.edu.cn

Abstract

Highly chemoselective and stereoselective tandem Pauson–Khand/[4+2] cycloaddition leads to efficient construction of the spirotricyclic core analogue of mangicol A.

Graphical abstract: A quick access to the spirotricyclic core analogue of mangicol A by a Rh(i)-catalyzed tandem Pauson–Khand/[4+2] cycloaddition

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Publication details

The article was received on 12 Oct 2012, accepted on 06 Nov 2012 and first published on 07 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC37465J
Citation: Chem. Commun., 2013,49, 170-172
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    A quick access to the spirotricyclic core analogue of mangicol A by a Rh(I)-catalyzed tandem Pauson–Khand/[4+2] cycloaddition

    W. Chen, J. Tay, J. Ying, M. Sabat, X. Yu and L. Pu, Chem. Commun., 2013, 49, 170
    DOI: 10.1039/C2CC37465J

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