Metal-only Lewis pairs featuring unsupported Pt→M (M = Zn or Cd) dative bonds

Mengtao Ma; Anastas Sidiropoulos; Lalrempuia Ralte; Andreas Stasch; Cameron Jones

doi:10.1039/C2CC37442K

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Metal-only Lewis pairs featuring unsupported Pt→M (M = Zn or Cd) dative bonds

Mengtao Ma,^a Anastas Sidiropoulos,^a Lalrempuia Ralte,^a Andreas Stasch*^a and Cameron Jones*^a

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School of Chemistry, Monash University, PO Box 23, Melbourne, Australia
E-mail: cameron.jones@monash.edu ;
Fax: +61-3-9905-4597 ;
Tel: +61-3-9902-0391

Chem. Commun., 2013,49, 48-50

DOI: 10.1039/C2CC37442K
Received 12 Oct 2012, Accepted 02 Nov 2012
First published online 05 Nov 2012

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Abstract
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Reactions of [Pt(PCy₃)₂] (Cy = cyclohexyl) with group 12 metal dihalides have afforded the novel metal only Lewis pair (MOLP) complexes, [(Cy₃P)₂Pt→MX₂] (M = Zn or Cd, X = Br or I), or the oxidative addition product, trans-[(Cy₃P)₂(I)PtHgI]. The zinc complex represents the first MOLP to contain an unsupported Pt→Zn linkage.

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Mengtao Ma
Anastas Sidiropoulos
Lalrempuia Ralte
Andreas Stasch
Cameron Jones

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