Concave trisoctahedral Ag3PO4 microcrystals with high-index facets and enhanced photocatalytic properties

Zhengbo Jiao; Yan Zhang; Hongchao Yu; Gongxuan Lu; Jinhua Ye; Yingpu Bi

doi:10.1039/C2CC37324F

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Concave trisoctahedral Ag₃PO₄ microcrystals with high-index facets and enhanced photocatalytic properties

Zhengbo Jiao,^a Yan Zhang,^a Hongchao Yu,^a Gongxuan Lu,^a Jinhua Ye^b and Yingpu Bi*^a

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State Key Laboratory for Oxo Synthesis & Selective Oxidation, and National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, CAS, Lanzhou 730000, China
E-mail: yingpubi@licp.cas.cn

International Center for Materials Nanoarchitectonics (MANA), and Research Unit for Environmental Remediation Materials, National Institute for Materials Science (NIMS), Tsukuba, Japan

Chem. Commun., 2013,49, 636-638

DOI: 10.1039/C2CC37324F
Received 08 Oct 2012, Accepted 26 Nov 2012
First published online 26 Nov 2012

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Herein, we demonstrate for the first time the fabrication of concave trisoctahedral Ag₃PO₄ microcrystals enclosed by {221} and {332} facets based on the heteroepitaxial growth procedure, which exhibit much higher photocatalytic activities than cubic Ag₃PO₄ and commercial N-doped TiO₂.

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Zhengbo Jiao
Yan Zhang
Hongchao Yu
Gongxuan Lu
Jinhua Ye
Yingpu Bi

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Concave trisoctahedral Ag₃PO₄ microcrystals with high-index facets and enhanced photocatalytic properties