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Issue 39, 2013
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Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes

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Abstract

A germylyne complex Cp*(CO)2W[triple bond, length as m-dash]GeC(SiMe3)3 (1) reacted with alcohols to give simple nucleophilic addition products, while 1 reacted with two molecules of arylaldehydes consecutively to give base-stabilised alkoxy(germylene) complexes via C–H bond activation and hydrogermylation.

Graphical abstract: Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes

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Publication details

The article was received on 01 Oct 2012, accepted on 01 Nov 2012 and first published on 02 Nov 2012


Article type: Communication
DOI: 10.1039/C2CC37126J
Citation: Chem. Commun., 2013,49, 4232-4234
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    Reactions of a tungsten–germylyne complex with alcohols and arylaldehydes

    T. Fukuda, H. Hashimoto and H. Tobita, Chem. Commun., 2013, 49, 4232
    DOI: 10.1039/C2CC37126J

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