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A novel and efficient palladium-catalysed direct di-heteroarylation of 1,2-dichloroperfluorocyclopentene with a variety of heteroarenes is reported, giving rise to 1,2-di(heteroaryl)ylperfluorocyclopentene photochromic compounds. The reaction proceeds with thiazoles, thiophenes or furan derivatives and tolerates various substituents.
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