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Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: matsuo@chem.s.u-tokyo.ac.jp
; Fax: +81 3-5800-6889
Chem. Commun., 2013,49, 279-281
DOI:
10.1039/C2CC36988E
Received
26 Sep 2012,
Accepted
08 Nov 2012
First published online
08 Nov 2012
A new type of acceptor–donor2 dyad system containing two magnesium porphyrin molecules and a fullerene molecule is much more stable than the magnesium porphyrin itself. When it is fabricated into a binary system using imidazole carboxylic acid as a linker to indium tin oxide, the molecule effects efficient photocurrent generation that surpasses the device using the corresponding zinc porphyrin.
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