Carbonylation of amines in methanol in the presence of NaIO4 produces formamide derivatives in good to excellent yields without a transition metal catalyst.
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Oxidative carbonylation of amines to formamides using NaIO4
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Department of Chemistry and Center for Catalysis, University of Florida, Gainesville, USA
E-mail: lmwhite@chem.ufl.edu ;
Tel: +1 (0)352-392-8768
E-mail: lmwhite@chem.ufl.edu ;
Tel: +1 (0)352-392-8768
Chem. Commun., 2012,48, 11310-11312
DOI: 10.1039/C2CC36809A
Received 17 Apr 2012, Accepted 08 Oct 2012
First published online 09 Oct 2012
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