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Issue 96, 2012
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Anomalous Staudinger reaction at intramolecular frustrated P–B Lewis pair frameworks

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Abstract

The FLP-mesityl azide addition products 5, formed by FLP-addition to the terminal azide nitrogen atom, undergo N–N bond cleavage in an unusual variant of the Staudinger reaction upon thermolysis or photolysis to give an internally borane stabilized [P][double bond, length as m-dash]NH phosphinimine and a dimethylindazole derivative.

Graphical abstract: Anomalous Staudinger reaction at intramolecular frustrated P–B Lewis pair frameworks

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Publication details

The article was received on 18 Sep 2012, accepted on 15 Oct 2012, published on 31 Oct 2012 and first published online on 31 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC36782C
Citation: Chem. Commun., 2012,48, 11739-11741
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    Anomalous Staudinger reaction at intramolecular frustrated P–B Lewis pair frameworks

    A. Stute, L. Heletta, R. Fröhlich, C. G. Daniliuc, G. Kehr and G. Erker, Chem. Commun., 2012, 48, 11739
    DOI: 10.1039/C2CC36782C

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