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State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P.R. China
; Fax: +86-25-83314502
Chem. Commun., 2013,49, 555-557
14 Sep 2012,
25 Oct 2012
First published online
01 Nov 2012
A highly connected 3D metal–organic framework with tfz-d topology based on Zn6O2 clusters and flexible carboxylate ligands has been synthesized. The obtained Zn-MOF shows solvatochromic behavior for fluorescence sensing of small molecules, gas adsorption properties and exceptional chemical stability and might have applications for separation and detection purposes.
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