An iron-catalyzed benzylic vinylation was developed to transfer the carbon atom in the N,N-dimethyl moiety of N,N-dimethylacetamide (or N,N-dimethylformamide) to 2-methyl azaarenes to generate 2-vinyl azaarenes.
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Highly efficient vinylaromatics generation via iron-catalyzed sp3 C–H bond functionalization CDC reaction: a novel approach to preparing substituted benzo[α]phenazines
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Catalytic Hydrogenation Research Center, State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, P. R. China
E-mail: greenchem@zjut.edu.cn ;
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Tel: +86 571 8832 0066
E-mail: greenchem@zjut.edu.cn ;
Fax: +86 571 8832 0066 ;
Tel: +86 571 8832 0066
Chem. Commun., 2012,48, 11993-11995
DOI: 10.1039/C2CC36708D
Received 14 Sep 2012, Accepted 25 Oct 2012
First published online 25 Oct 2012
Chemical Communications
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