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Center for Smart Supramolecules, Department of Chemistry and Division of Advanced Materials Science, Pohang University of Science and Technology, San 31 Hyojadong, Pohang 790-784, Republic of Korea
; Fax: +82-54-279-8129
; Tel: +82-54-279-2113
Chem. Commun., 2012,48, 11650-11652
13 Sep 2012,
19 Oct 2012
First published online
22 Oct 2012
A metal–organic framework (MOF), NH2-MIL-101(Al), which acts as a bifunctional, site-isolated Lewis acid–Brønsted base heterogeneous catalyst, catalyzes a tandem Meinwald rearrangement–Knoevenagel condensation reaction with remarkable substrate selectivity.
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