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Washington University in St. Louis, Department of Mechanical Engineering and Materials Science, 1 Brookings Dr., St. Louis, USA
E-mail: singamaneni@wustl.edu
; Fax: +1 314-935-4014
; Tel: +1 314-935-5407
Chem. Commun., 2012,48, 11540-11542
DOI:
10.1039/C2CC36675D
Received
13 Sep 2012,
Accepted
11 Oct 2012
First published online
12 Oct 2012
In this communication, we describe the covalent assembly of gold nanoparticles into core–satellite clusters using the “cream of the crop” Click reaction, namely, azide–alkyne Huisgen 1,3-dipolar cycloaddition. Surface enhanced Raman scattering (SERS), localized surface plasmon resonance (LSPR) spectroscopy, transmission electron microscopy (TEM) and dynamic light scattering (DLS) confirm the successful “Click” between the plasmonic cores and satellites.
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