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Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India
E-mail: r.banerjee@ncl.res.in
; Fax: +91 2025902535
Chem. Commun., 2012,48, 11868-11870
DOI:
10.1039/C2CC36651G
Received
13 Sep 2012,
Accepted
18 Oct 2012
First published online
18 Oct 2012
Here we report a highly porous, water stable Co based ZIF [CoNIm (RHO)] and its solution mediated phase transformation to a less porous and water unstable ZIF [CoNIm (SOD)]. CoNIm (RHO) has high Langmuir surface area [2087 m2 g−1] as well as high water adsorption [200 cm3 (STP) g−1] capacity.
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