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Issue 91, 2012
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Facile synthesis of nitriles via manganese oxide promoted oxidative dehydrosulfurization of primary thioamides

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Abstract

In the presence of manganese oxides, dehydrosulfurization of various kinds of primary thioamides including aromatic, heterocyclic, and aliphatic ones efficiently proceeded to give the corresponding nitriles in high yields. The observed catalysis was truly heterogeneous, and manganese oxides could be reused.

Graphical abstract: Facile synthesis of nitriles via manganese oxide promoted oxidative dehydrosulfurization of primary thioamides

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Publication details

The article was received on 12 Sep 2012, accepted on 01 Oct 2012, published on 03 Oct 2012 and first published online on 03 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC36635E
Citation: Chem. Commun., 2012,48, 11247-11249
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    Facile synthesis of nitriles via manganese oxide promoted oxidative dehydrosulfurization of primary thioamides

    K. Yamaguchi, K. Yajima and N. Mizuno, Chem. Commun., 2012, 48, 11247
    DOI: 10.1039/C2CC36635E

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