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Issue 93, 2012
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1,5-Migration of rhodium via C–H bond activation in catalytic decyanative silylation of nitriles

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Abstract

Unprecedented aryl-to-aryl 1,5-rhodium migration is involved in decyanative silylation of aryl cyanides bearing a tethered arene. The 1,5-migration proceeds through remote C–H bond activation. 1,5-Migration also occurs in other rhodium-catalyzed reactions, including borylation and oxidative Mizoroki–Heck reactions.

Graphical abstract: 1,5-Migration of rhodium via C–H bond activation in catalytic decyanative silylation of nitriles

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Publication details

The article was received on 11 Sep 2012, accepted on 10 Oct 2012 and first published on 11 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC36601K
Citation: Chem. Commun., 2012,48, 11437-11439
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    1,5-Migration of rhodium via C–H bond activation in catalytic decyanative silylation of nitriles

    M. Tobisu, J. Hasegawa, Y. Kita, H. Kinuta and N. Chatani, Chem. Commun., 2012, 48, 11437
    DOI: 10.1039/C2CC36601K

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