Two-component gelation and morphology-dependent conductivity of a naphthalene-diimide (NDI) π-system by orthogonal hydrogen bonding

Haridas Kar; Mijanur Rahaman Molla; Suhrit Ghosh

doi:10.1039/C2CC36536G

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Chemical Communications

Issue 39, 2013

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Two-component gelation and morphology-dependent conductivity of a naphthalene-diimide (NDI) π-system by orthogonal hydrogen bonding

Haridas Kar,^a Mijanur Rahaman Molla^a and Suhrit Ghosh*^a

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Indian Association for the Cultivation of Science, Polymer Science Unit, 2A & 2B Raja S. C. Mullick Rd., Kolkata, India
E-mail: psusg2@iacs.res.in ;
Fax: +91 33 2473 2805 ;
Tel: +91 33 2473 4971

Chem. Commun., 2013,49, 4220-4222

DOI: 10.1039/C2CC36536G
Received 07 Sep 2012, Accepted 04 Oct 2012
First published online 05 Oct 2012

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The utility of an external structure-directing agent to induce orthogonal H-bonding-mediated programmed supramolecular-assembly and gelation of an n-type NDI chromophore is reported. Further, the effect of π-stacking and morphology on electrical conductivity of semiconducting NDI building blocks is revealed.

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Two-component gelation and morphology-dependent conductivity of a naphthalene-diimide (NDI) π-system by orthogonal hydrogen bonding

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