The kinetics of the reaction of peroxyl and dpph˙ radicals with phenols H-bonded to N-bases have been studied for the first time. Electron-transfer processes are observed in MeCN but only with the dpph˙ radical.
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Proton–electron transfer pathways in the reactions of peroxyl and dpph˙ radicals with hydrogen-bonded phenols
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a
Department of Chemistry “Ciamician”, University of Bologna, Via San Giacomo 11, Bologna, Italy
E-mail: riccardo.amorati@unibo.it ;
Fax: +39 051 209 5688 ;
Tel: +39 051 209 5689
E-mail: riccardo.amorati@unibo.it ;
Fax: +39 051 209 5688 ;
Tel: +39 051 209 5689
b
Department of Chemistry “U. Schiff”, University of Firenze, Via della Lastruccia, 3-13, Sesto Fiorentino, Italy
c
Istituto di Chimica Biomolecolare, Consiglio Nazionale delle Ricerche, Via Paolo Gaifami, 18, Catania, Italy
E-mail: mario.foti@cnr.it ;
Fax: +39 095 733 8310 ;
Tel: +39 095 733 8343
E-mail: mario.foti@cnr.it ;
Fax: +39 095 733 8310 ;
Tel: +39 095 733 8343
Chem. Commun., 2012,48, 11904-11906
DOI: 10.1039/C2CC36531F
Received 07 Sep 2012, Accepted 24 Oct 2012
First published online 24 Oct 2012
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