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Issue 92, 2012
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Silyl-migrations in frustrated Lewis pair chemistry: reactions of ((CH3)3Si)3P and B(C6F4H)3 with H2 and CO2

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Abstract

The 1 : 1 mixture of tris(trimethylsilyl)phosphine and tris(2,3,5,6-tetrafluorophenyl)borane behaves as frustrated Lewis pair (FLP) and shows H2 and sequential two-step double CO2 activation with subsequent Me3Si group transfer.

Graphical abstract: Silyl-migrations in frustrated Lewis pair chemistry: reactions of ((CH3)3Si)3P and B(C6F4H)3 with H2 and CO2

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Publication details

The article was received on 05 Sep 2012, accepted on 09 Oct 2012 and first published on 09 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC36470K
Citation: Chem. Commun., 2012,48, 11304-11306
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    Silyl-migrations in frustrated Lewis pair chemistry: reactions of ((CH3)3Si)3P and B(C6F4H)3 with H2 and CO2

    K. Takeuchi and D. W. Stephan, Chem. Commun., 2012, 48, 11304
    DOI: 10.1039/C2CC36470K

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