Shape-conserving enhancement of vibrational circular dichroism in lanthanide complexes

Samuele Lo Piano; Sebastiano Di Pietro; Lorenzo Di Bari

doi:10.1039/C2CC36455G

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Chemical Communications

Issue 98, 2012

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Impact Factor 6.169 100 Issues per Year Indexed in MEDLINE

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Shape-conserving enhancement of vibrational circular dichroism in lanthanide complexes

Samuele Lo Piano,^a Sebastiano Di Pietro^b and Lorenzo Di Bari*^b

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Scuola Normale Superiore, Piazza Cavalieri 7, I-56126 Pisa, Italy

Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, Pisa, Italy
E-mail: ldb@dcci.unipi.it ;
Fax: +39 050 2219 260

Chem. Commun., 2012,48, 11996-11998

DOI: 10.1039/C2CC36455G
Received 04 Sep 2012, Accepted 25 Oct 2012
First published online 25 Oct 2012

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The VCD spectra of lanthanide chelates with two chiral ligands display conserved sequences of bands throughout the Ln series. Some compounds (Tm, Yb) feature increased bands and strongly improved signal-to-noise ratios, an effect we dub Lanthanide Induced VCD Enhancement (LIVE).

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