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Issue 7, 2013
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Chirality transfer based on reversible C–C bond formation/breaking in nickel(II) complexes

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Abstract

The reaction of (1R)-(−)-myrtenal-derived benzothiazoline with nickel(II) acetate in ethanol exclusively gave a Schiff base-type nickel(II) complex having M helical configurational myrtenyl arms, which is reversibly converted to a non-innocent-type complex having additional S,S configurational asymmetric carbon centres.

Graphical abstract: Chirality transfer based on reversible C–C bond formation/breaking in nickel(ii) complexes

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Publication details

The article was received on 31 Aug 2012, accepted on 08 Oct 2012 and first published on 23 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC36332A
Citation: Chem. Commun., 2013,49, 668-670
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    Chirality transfer based on reversible C–C bond formation/breaking in nickel(II) complexes

    T. Kawamoto, N. Suzuki, T. Ono, D. Gong and T. Konno, Chem. Commun., 2013, 49, 668
    DOI: 10.1039/C2CC36332A

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