Electron-transfer properties of a nonheme manganese(IV)–oxo complex acting as a stronger one-electron oxidant than the iron(IV)–oxo analogue

Heejung Yoon; Yuma Morimoto; Yong-Min Lee; Wonwoo Nam; Shunichi Fukuzumi

doi:10.1039/C2CC36291K

This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.

skip RSC | ChemSpider | Feedback

Home > Journals > Chemical Communications > Electron-transfer prope...

For Authors & Referees | For Librarians | For Members

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Chemical Communications

Issue 91, 2012

Urgent high quality communications from across the chemical sciences.

Impact Factor 6.169 100 Issues per Year Indexed in MEDLINE

Journal Home

Previous Article | Next Article

Communication

Electron-transfer properties of a nonheme manganese(IV)–oxo complex acting as a stronger one-electron oxidant than the iron(IV)–oxo analogue

Heejung Yoon,^a Yuma Morimoto,^b Yong-Min Lee,^a Wonwoo Nam*^a and Shunichi Fukuzumi*^a^b

Show Affiliations

Hide Affiliations

Corresponding authors

Department of Bioinspired Science, Ewha Womans University, Seoul, Korea
E-mail: wwnam@ewha.ac.kr

Department of Material and Life Science, Graduate School of Engineering, Osaka University and ALCA (JST), 2-1 Yamada-oka, Suita, Japan
E-mail: fukuzumi@chem.eng.osaka-u.jp

Chem. Commun., 2012,48, 11187-11189

DOI: 10.1039/C2CC36291K
Received 30 Aug 2012, Accepted 19 Sep 2012
First published online 21 Sep 2012

Please wait while Download options loads

Download Citation

Request Permissions

Abstract
Cited by
Related Content

Electron-transfer properties of a nonheme Mn(IV)–oxo complex, [(Bn-TPEN)Mn^IV(O)]²⁺, reveals that Mn(IV)–oxo complex acts as a stronger one-electron oxidant than the Fe(IV)–oxo analogue. As a result, an electron transfer process in N-dealkylation has been detected by a transient radical cation intermediate, para-Me-DMA˙⁺, in the oxidation of para-Me-DMA by [(Bn-TPEN)Mn^IV(O)]²⁺.

Chemical Communications - Information Point

About this Journal

People and Contacts

Submit to this Journal

Editorial Board

Authors and Referees

Subscription Information

Follow Journal | |

Supplementary Info

Supplementary information
PDF (322K)

Search Articles By

Heejung Yoon
Yuma Morimoto
Yong-Min Lee
Wonwoo Nam
Shunichi Fukuzumi

Terms & Conditions|Privacy and Cookies |Accessibility|ACAP Enabled

Chemical Communications

Electron-transfer properties of a nonheme manganese(IV)–oxo complex acting as a stronger one-electron oxidant than the iron(IV)–oxo analogue

Log in (Free Access)

Log in (Subscriber Access)

Supplementary Info

Search Articles By

Chemical Communications

Electron-transfer properties of a nonheme manganese(IV)–oxo complex acting as a stronger one-electron oxidant than the iron(IV)–oxo analogue

This text is added as a work around for heading error in Accessibility testing

Log in (Free Access)

Log in (Subscriber Access)

Supplementary Info

Search Articles By