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Issue 91, 2012
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Electron-transfer properties of a nonheme manganese(IV)–oxo complex acting as a stronger one-electron oxidant than the iron(IV)–oxo analogue

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Abstract

Electron-transfer properties of a nonheme Mn(IV)–oxo complex, [(Bn-TPEN)MnIV(O)]2+, reveals that Mn(IV)–oxo complex acts as a stronger one-electron oxidant than the Fe(IV)–oxo analogue. As a result, an electron transfer process in N-dealkylation has been detected by a transient radical cation intermediate, para-Me-DMA˙+, in the oxidation of para-Me-DMA by [(Bn-TPEN)MnIV(O)]2+.

Graphical abstract: Electron-transfer properties of a nonheme manganese(iv)–oxo complex acting as a stronger one-electron oxidant than the iron(iv)–oxo analogue

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Publication details

The article was received on 30 Aug 2012, accepted on 19 Sep 2012, published on 21 Sep 2012 and first published online on 21 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC36291K
Citation: Chem. Commun., 2012,48, 11187-11189
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    Electron-transfer properties of a nonheme manganese(IV)–oxo complex acting as a stronger one-electron oxidant than the iron(IV)–oxo analogue

    H. Yoon, Y. Morimoto, Y. Lee, W. Nam and S. Fukuzumi, Chem. Commun., 2012, 48, 11187
    DOI: 10.1039/C2CC36291K

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