Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity

Daniel P. Iwaniuk; Christian Wolf

doi:10.1039/C2CC36267H

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Chemical Communications

Issue 91, 2012

Urgent high quality communications from across the chemical sciences.

Impact Factor 6.169 100 Issues per Year Indexed in MEDLINE

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Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity

Daniel P. Iwaniuk^a and Christian Wolf*^a

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Department of Chemistry, Georgetown University, Washington, USA
E-mail: cw27@georgetown.edu ;
Fax: +1 202 687 6209 ;
Tel: +1 202 687 3468

Chem. Commun., 2012,48, 11226-11228

DOI: 10.1039/C2CC36267H
Received 28 Aug 2012, Accepted 29 Sep 2012
First published online 03 Oct 2012

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A rationally designed stereodynamic ICD probe carrying two terminal amino functions for chemo- and enantioselective sensing of citronellal is introduced. The sensor shows strong Cotton effects upon diimine formation which can be used for accurate ee determination.

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