Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90–95% ee).
Urgent high quality communications from across the chemical sciences.
Impact Factor
6.169
100 Issues per Year
Indexed in MEDLINE
Communication
γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes
Show Affiliations
Hide Affiliations
*
Corresponding authors
a
Department of Chemistry, University of Nebraska-Lincoln, Lincoln, USA
E-mail: jtakacs1@unl.edu ;
Fax: +1 402 472-9402 ;
Tel: +1 402 472-6232
E-mail: jtakacs1@unl.edu ;
Fax: +1 402 472-9402 ;
Tel: +1 402 472-6232
b
Department of Chemistry and Physics, Purdue University Calumet, Indiana, USA
Chem. Commun., 2012,48, 12180-12182
DOI: 10.1039/C2CC36199J
Received 26 Aug 2012, Accepted 31 Oct 2012
First published online 01 Nov 2012
Chemical Communications
- Information Point
Supplementary Info
-
Supplementary information
PDF (1749K) -
Supplementary information
PDF (13956K)