A cationic ruthenium(II) catalyst enabled highly efficient oxidative alkenylations of electron-rich arenes bearing removable, weakly coordinating carbamates, and allowed for cross-dehydrogenative C–H bond functionalization in an aerobic manner.
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Ruthenium-catalyzed oxidative C–H alkenylation of aryl carbamates
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Institut fuer Organische und Biomolekulare Chemie, Georg-August-Universitaet, Tammannstrasse 2, 37077 Goettingen, Germany
E-mail: Lutz.Ackermann@chemie.uni-goettingen.de ;
Fax: +49 551 396777
E-mail: Lutz.Ackermann@chemie.uni-goettingen.de ;
Fax: +49 551 396777
Chem. Commun., 2012,48, 11343-11345
DOI: 10.1039/C2CC36196E
Received 25 Aug 2012, Accepted 04 Oct 2012
First published online 05 Oct 2012
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