Jump to main content
Jump to site search

Issue 90, 2012
Previous Article Next Article

Splitting of dihydrogen by five-membered zirconacycloallenoids: a novel pathway to conjugated diene zirconocene complexes

Author affiliations

Abstract

The five-membered zirconacycloallenoids 2 react rapidly with dihydrogen under mild conditions to yield the corresponding (s-cis-conjugated diene)zirconocenes 3. The reaction involves splitting of the H2 molecule between the metal center and a ligand carbon atom.

Graphical abstract: Splitting of dihydrogen by five-membered zirconacycloallenoids: a novel pathway to conjugated diene zirconocene complexes

Back to tab navigation

Supplementary files

Publication details

The article was received on 25 Aug 2012, accepted on 19 Sep 2012 and first published on 21 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC36189B
Citation: Chem. Commun., 2012,48, 11085-11087
  •   Request permissions

    Splitting of dihydrogen by five-membered zirconacycloallenoids: a novel pathway to conjugated diene zirconocene complexes

    G. Bender, G. Kehr, C. G. Daniliuc, Q. M. Dao, S. Ehrlich, S. Grimme and G. Erker, Chem. Commun., 2012, 48, 11085
    DOI: 10.1039/C2CC36189B

Search articles by author

Spotlight

Advertisements