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Issue 91, 2012
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Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes: efficient access to (Z,E)-dienamides

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Abstract

Ruthenium- and rhodium-catalyzed direct oxidative cross-coupling reactions of acrylamides with alkenes were developed. These methods provide an efficient route for the synthesis of (Z,E)-dienamides in excellent yields with good stereoselectivity. The catalytic systems allowed oxidative olefination of a wide range of alkenes bearing different functional groups, such as CO2R, COMe, SO2Ph, aryl, CONHBn, CN, PO(OEt)2, as well as Weinreb amide.

Graphical abstract: Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes: efficient access to (Z,E)-dienamides

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The article was received on 23 Aug 2012, accepted on 30 Sep 2012 and first published on 15 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC36137J
Citation: Chem. Commun., 2012,48, 11232-11234
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    Ruthenium- and rhodium-catalyzed cross-coupling reaction of acrylamides with alkenes: efficient access to (Z,E)-dienamides

    J. Zhang and T. Loh, Chem. Commun., 2012, 48, 11232
    DOI: 10.1039/C2CC36137J

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