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Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry & Chemical Engineering of Guangxi Normal University, Guilin 541004, P. R. China
; Fax: +86(0)773-2120958
Chem. Commun., 2012,48, 11689-11691
21 Aug 2012,
12 Oct 2012
First published online
17 Oct 2012
Eighteen Cu(II) ions are consolidated by simple inorganic linkers alone to construct an S6-symmetric six-bladed impeller-like Cu18 nanocluster driven by the concomitant decomposition reaction of a Schiff base, which affords a typical high-nuclearity inorganic cluster and a representative synthetic strategy. The magnetic measurements reveal dominant antiferromagnetic interaction in this cluster.
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