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The Institute of Scientific and Industrial Research (SANKEN), Osaka University, Mihogaoka 8-1, Ibaraki, Japan
E-mail: fuji@sanken.osaka-u.ac.jp
; Fax: +81 6-6879-8499
; Tel: +81 6-6879-8495
Chem. Commun., 2012,48, 11008-11010
DOI:
10.1039/C2CC36054C
Received
21 Aug 2012,
Accepted
23 Sep 2012
First published online
24 Sep 2012
Excess electron transfer dynamics in DNA hairpins was investigated by femtosecond laser flash photolysis of a donor–DNA–acceptor system using N,N-dimethylaminopyrene and diphenylacetylene as an electron donor and acceptor, respectively. It was revealed that the excess electron hopping rate between T's is faster than that of the hole.
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