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Issue 91, 2012
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Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines

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Abstract

Highly efficient synthesis of 3-hydroxypyridines has been developed based on carbenoid-mediated N–O bond insertion. Treatment of δ-diazo oxime ethers with dirhodium complex Rh2(tfacam)4 rapidly provides a variety of pyridines in 5–10 minutes in good to excellent yields.

Graphical abstract: Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines

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Publication details

The article was received on 18 Aug 2012, accepted on 25 Sep 2012 and first published on 26 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC36009H
Citation: Chem. Commun., 2012,48, 11244-11246
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    Carbenoid-mediated N–O bond insertion and its application in the synthesis of pyridines

    X. Qi, L. Dai and C. Park, Chem. Commun., 2012, 48, 11244
    DOI: 10.1039/C2CC36009H

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