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Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: lzwu@mail.ipc.ac.cn
; Fax: +86 108254 3580
; Tel: +86 108254 3580
Chem. Commun., 2012,48, 10886-10888
DOI:
10.1039/C2CC35960J
Received
17 Aug 2012,
Accepted
18 Sep 2012
First published online
19 Sep 2012
An amphiphilic cationic platinum(II) terpyridyl complex 1 with a redox ferrocene unit has been demonstrated to form well-defined vesicular architectures that could be disrupted and regenerated reversibly by multi-stimuli in water. The hydrophobic and hydrophilic alternation of 1 was achieved via modulating its intramolecular ILCT state to MLCT state.
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