A regioselective approach for the synthesis of pyrrolopyridinones and pyrroloazepinones is reported employing an Ugi reaction followed by a gold(I) or platinum(II) catalyzed intramolecular hydroarylation.
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Gold(I) and platinum(II) switch: a post-Ugi intramolecular hydroarylation to pyrrolopyridinones and pyrroloazepinones
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a
Laboratory for Organic & Microwave-Assisted Chemistry (LOMAC), Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Leuven, Belgium
E-mail: erik.vandereycken@chem.kuleuven.be
E-mail: erik.vandereycken@chem.kuleuven.be
b
Bioorganic Laboratory, Department of Chemistry, University of Delhi, Delhi-110 007, India
Chem. Commun., 2012,48, 10916-10918
DOI: 10.1039/C2CC35900F
Received 15 Aug 2012, Accepted 17 Sep 2012
First published online 18 Sep 2012
Chemical Communications
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