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Issue 87, 2012
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Planarized B-phenylborataanthracene anions: structural and electronic impacts of coplanar constraint

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Abstract

Potassium and lithium salts of anionic B-phenylborataanthracenes, whose phenyl groups were fixed in a coplanar fashion, were synthesized. These compounds exhibited solvent-separated ion pair structures both in the crystalline state and in solution. Planarization of the phenyl moiety had a remarkable impact on the photophysical properties, such as the red-shifted absorption and intense fluorescence.

Graphical abstract: Planarized B-phenylborataanthracene anions: structural and electronic impacts of coplanar constraint

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Publication details

The article was received on 14 Aug 2012, accepted on 31 Aug 2012, published on 31 Aug 2012 and first published online on 31 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC35874C
Citation: Chem. Commun., 2012,48, 10715-10717
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    Planarized B-phenylborataanthracene anions: structural and electronic impacts of coplanar constraint

    T. Kushida, Z. Zhou, A. Wakamiya and S. Yamaguchi, Chem. Commun., 2012, 48, 10715
    DOI: 10.1039/C2CC35874C

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