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Issue 39, 2013
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Facile carbon–sulfur bond cleavage in diarylsulfonium ylides: a catalytic sulfur-to-silicon group transfer

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Abstract

An unusual cleavage of the non-ylidic carbon–sulfur bond of a sulfonium ylide is reported. The reaction can be catalysed by a variety of palladium(II) complexes under mild conditions. Preliminary results show that coordination of the ylide to the metal center results in significant structural changes.

Graphical abstract: Facile carbon–sulfur bond cleavage in diarylsulfonium ylides: a catalytic sulfur-to-silicon group transfer

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Publication details

The article was received on 08 Aug 2012, accepted on 10 Sep 2012 and first published on 11 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC35762C
Citation: Chem. Commun., 2013,49, 4292-4294
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    Facile carbon–sulfur bond cleavage in diarylsulfonium ylides: a catalytic sulfur-to-silicon group transfer

    X. Huang, R. Goddard and N. Maulide, Chem. Commun., 2013, 49, 4292
    DOI: 10.1039/C2CC35762C

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