The Fe(IV)oxo complex of a coordinatively flexible multidentate mono-carboxylato ligand is obtained by the one electron oxidation of a low spin Fe(III) precursor in water.
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An aqueous non-heme Fe(IV)oxo complex with a basic group in the second coordination sphere
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a
Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, 5230 Odense M, Denmark
E-mail: mckenzie@sdu.dk ;
Fax: (+45) 6615 8760 ;
Tel: (+45) 6550 2518
E-mail: mckenzie@sdu.dk ;
Fax: (+45) 6615 8760 ;
Tel: (+45) 6550 2518
b
Department of Chemistry, University of Oxford, South Parks Road, Oxford, UK
c
Department of Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark
Chem. Commun., 2012,48, 10880-10882
DOI: 10.1039/C2CC35746A
Received 08 Aug 2012, Accepted 14 Sep 2012
First published online 02 Oct 2012
Chemical Communications
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