Gate adsorption of CO2 on a flexible one-dimensional copper-based coordination polymer crystal

Ryosuke Kotani; Atsushi Kondo; Kazuyuki Maeda

doi:10.1039/C2CC35739A

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Chemical Communications

Issue 92, 2012

Urgent high quality communications from across the chemical sciences.

Impact Factor 6.169 100 Issues per Year Indexed in MEDLINE

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Gate adsorption of CO₂ on a flexible one-dimensional copper-based coordination polymer crystal

Ryosuke Kotani,^a Atsushi Kondo*^a and Kazuyuki Maeda*^a

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Department of Applied Chemistry, Faculty of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Japan
E-mail: kondoa@cc.tuat.ac.jp ;
Fax: +81 42 388 7040 ;
Tel: +81 42 388 7040

Chem. Commun., 2012,48, 11316-11318

DOI: 10.1039/C2CC35739A
Received 08 Aug 2012, Accepted 04 Oct 2012
First published online 18 Oct 2012

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Abstract
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A flexible one-dimensional copper-based coordination polymer (CP) crystal was synthesized and the crystal structure was solved. This CP crystal shows a single step gate adsorption uptake of CO₂ under moderate conditions (268 K ≤ T ≤ 303 K, P < 1 atm) irrespective of no N₂ uptake at 77 K.

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Gate adsorption of CO₂ on a flexible one-dimensional copper-based coordination polymer crystal