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Issue 84, 2012
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Deciphering DNA-based asymmetric catalysis through intramolecular Friedel–Crafts alkylations

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Abstract

We describe asymmetric intramolecular Friedel–Crafts alkylations with a DNA-based hybrid catalyst and propose a plausible binding model. This study shows promise for studying relationships between the helical chirality of DNA and enantioselectivity of the chemical reaction.

Graphical abstract: Deciphering DNA-based asymmetric catalysis through intramolecular Friedel–Crafts alkylations

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Publication details

The article was received on 17 May 2012, accepted on 03 Sep 2012, published on 03 Sep 2012 and first published online on 03 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC35625B
Citation: Chem. Commun., 2012,48, 10398-10400
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    Deciphering DNA-based asymmetric catalysis through intramolecular Friedel–Crafts alkylations

    S. Park, K. Ikehata, R. Watabe, Y. Hidaka, A. Rajendran and H. Sugiyama, Chem. Commun., 2012, 48, 10398
    DOI: 10.1039/C2CC35625B

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