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Issue 83, 2012
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Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

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Abstract

By intimate control of reaction conditions, phase-pure crystalline porous metal–organic framework materials [Zn4O(L)3] with interpenetrated and non-interpenetrated structures can be synthesised. Under certain conditions, these reactions occur with concomitant deprotection of masked alcohols located on the organic links which yield accessible ‘metal-binding’ functional groups within the frameworks.

Graphical abstract: Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

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Publication details

The article was received on 01 Aug 2012, accepted on 31 Aug 2012 and first published on 31 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC35565E
Citation: Chem. Commun., 2012,48, 10328-10330
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    Control of framework interpenetration for in situ modified hydroxyl functionalised IRMOFs

    D. Rankine, A. Avellaneda, M. R. Hill, C. J. Doonan and C. J. Sumby, Chem. Commun., 2012, 48, 10328
    DOI: 10.1039/C2CC35565E

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