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Issue 77, 2012
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A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state

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Abstract

Carbazole-containing porphyrinoid 3 was synthesised for the first time via Suzuki–Miyaura cross-coupling reaction. Oxidation with MnO2 yielded its porphyrin-state 2 featuring macrocyclic aromaticity in exchange for the loss of the resonance energies of the benzene rings.

Graphical abstract: A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state

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Publication details

The article was received on 31 Jul 2012, accepted on 09 Aug 2012 and first published on 09 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC35550G
Citation: Chem. Commun., 2012,48, 9640-9642
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    A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state

    L. Arnold, M. Baumgarten and K. Müllen, Chem. Commun., 2012, 48, 9640
    DOI: 10.1039/C2CC35550G

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