An imidazole-appended dipyrrin ligand yields, upon coordination to Cu(II) cations, a linear metallatecton that self-assembles with Cd(II) salts to afford 2D grid-type MOFs which, upon parallel stacking, lead to porous crystals offering 1D channels.
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Stepwise construction of grid-type Cu(II)–Cd(II) heterometallic MOFs based on an imidazole-appended dipyrrin ligand
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Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, Strasbourg, France
E-mail: hosseini@unistra.fr ;
Fax: +33 368851325 ;
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E-mail: hosseini@unistra.fr ;
Fax: +33 368851325 ;
Tel: +33 368851323
Chem. Commun., 2012,48, 10313-10315
DOI: 10.1039/C2CC35543D
Received 31 Jul 2012, Accepted 30 Aug 2012
First published online 31 Aug 2012
This article is part of themed collection:
Metal-organic frameworks
Chemical Communications
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