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Issue 83, 2012
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Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle

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Abstract

A chromiumtricarbonyl-bound iridacycle displays novel catalytic virtues for the conversion of terminal aromatic alkynes into racemic N-phenyl, 1-arylethylamines by tandem hydro-amination and hydrosilation/protodesilation reactions under mild “one pot” conditions.

Graphical abstract: Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle

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Publication details

The article was received on 30 Jul 2012, accepted on 30 Aug 2012 and first published on 31 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC35520E
Citation: Chem. Commun., 2012,48, 10310-10312
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    Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle

    W. Iali, F. L. Paglia, X. L. Goff, D. Sredojević, M. Pfeffer and J. Djukic, Chem. Commun., 2012, 48, 10310
    DOI: 10.1039/C2CC35520E

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