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Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, P.R.China
E-mail: xqyu@scu.edu.cn
; Fax: +86 28-8541-5886
Chem. Commun., 2012,48, 11769-11771
DOI:
10.1039/C2CC35468C
Received
28 Jul 2012,
Accepted
20 Oct 2012
First published online
22 Oct 2012
A novel iron-mediated direct C–H arylation of quinones and pyridine analogues with arylboronic acids has been developed using dichloromethane and water as solvents at ambient temperature. FeS is employed and serves as an efficient catalyst. A detailed reaction mechanism is speculated and expounded.