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MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: lutongbu@mail.sysu.edu.cn
; Fax: +86-20-84112921
Chem. Commun., 2012,48, 12002-12004
DOI:
10.1039/C2CC35461F
Received
27 Jul 2012,
Accepted
22 Oct 2012
First published online
05 Nov 2012
A μ4-Cl bridged anionic sodalite-type porous metal–organic framework (Et2NH2)3[(Cu4Cl)3(TTCA)8]·26DEF was synthesized, in which Et2NH2+ can be exchanged by Li+ cations. The results of gas measurements indicate that Et2NH2+ and Li+ are beneficial for methane and hydrogen storage, respectively.
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