An nBu4NI-catalyzed benzylic C–H acyloxylation of alkylarenes with readily available aromatic aldehydes has been developed. These reactions occur under mild and clean reaction conditions using tert-butyl hydroperoxide as the green terminal oxidant.
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Communication
Bu4NI-catalyzed benzylic acyloxylation of alkylarenes with aromatic aldehydes
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State Key Laboratory of Medicinal Chemical Biology, College of Pharmacy, Nankai University, 94 Weijin Road, Tianjin 300071, China
E-mail: wangbin@nankai.edu.cn ;
Fax: +86-22-23507760 ;
Tel: +86-22-23506290
E-mail: wangbin@nankai.edu.cn ;
Fax: +86-22-23507760 ;
Tel: +86-22-23506290
Chem. Commun., 2012,48, 10204-10206
DOI: 10.1039/C2CC35450K
Received 24 May 2012, Accepted 30 Aug 2012
First published online 30 Aug 2012
Chemical Communications
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