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JST, CREST, and Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto, Osaka 558-8585, Japan
; Fax: +81-6-6605-2560
; Tel: +81-6-6605-3139
Chem. Commun., 2012,48, 10954-10956
24 Jul 2012,
06 Sep 2012
First published online
10 Sep 2012
A Ca2+ complex with octadentate cyclen having three pyridines and one triazole on its sidearms mediated two-point chirality transfer from an external chiral source to the coordinating pyridine and coumarin moieties. The induced chirality information was repeatedly written, deleted, and rewritten by coupling with esterification of the coordinating external chiral anion.
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