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Issue 39, 2013
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Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation

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Abstract

Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes with an ene-1,2-dithiolate ligand are generated as models of the active sites of molybdenum hydroxylases. The sulfide and selenide groups are highly reactive toward triphenylphosphine in the order of Se > S.

Graphical abstract: Oxo-sulfido- and oxo-selenido-molybdenum(vi) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation

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Publication details

The article was received on 24 Jul 2012, accepted on 08 Oct 2012 and first published on 08 Oct 2012


Article type: Communication
DOI: 10.1039/C2CC35345H
Citation: Chem. Commun., 2013,49, 4358-4360
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    Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing a dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: low temperature preparation and characterisation

    H. Sugimoto, S. Tatemoto, K. Toyota, K. Ashikari, M. Kubo, T. Ogura and S. Itoh, Chem. Commun., 2013, 49, 4358
    DOI: 10.1039/C2CC35345H

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