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Issue 89, 2012
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Formal C–H amination of cyclopropenes

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Abstract

A novel C(sp3)–H amination of trimethylsilyl-substituted cyclopropenes is described. This C–H amination proceeds via a tandem regioselective ene reaction between cyclopropenes and azodicarboxylate to generate a hydrazodicarboxylate intermediate followed by its site-selective allylic transposition.

Graphical abstract: Formal C–H amination of cyclopropenes

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Publication details

The article was received on 24 Jul 2012, accepted on 20 Sep 2012 and first published on 24 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC35329F
Citation: Chem. Commun., 2012,48, 10990-10992
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    Formal C–H amination of cyclopropenes

    C. Sun, J. Li, D. Lee, G. Huang and Y. Xia, Chem. Commun., 2012, 48, 10990
    DOI: 10.1039/C2CC35329F

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