Metal-catalyzed direct C(sp3)–H bond amination of 2-alkyl azaarenes with N![[double bond, length as m-dash]](http://www.rsc.org/images/entities/char_e001.gif)
N double bonds has been developed, which expands the scope of C(sp3)–H bond activation reactions and provides a new access to medicinally important azaarene derivatives.
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Metal catalyzed C(sp3)–H bond amination of 2-alkyl azaarenes with diethyl azodicarboxylate
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a
College of Chemistry and Environmental Science, Key Laboratory of Green Chemical Media and Reactions of Ministry of Education, Henan Normal University, Xinxiang 453007, China
E-mail: quguir@sina.com ;
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E-mail: quguir@sina.com ;
Fax: +86 373 3329276 ;
Tel: +86 373 3329255
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School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China
Chem. Commun., 2012,48, 9723-9725
DOI: 10.1039/C2CC35309A
Received 23 Jul 2012, Accepted 14 Aug 2012
First published online 15 Aug 2012
Chemical Communications
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