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Issue 81, 2012
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nBu4NI-catalyzed direct synthesis of α-ketoamides from aryl methyl ketones with dialkylformamides in water using TBHP as oxidant

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Abstract

A novel and easy practical direct synthesis of α-ketoamides has been developed without metals in water. This procedure was catalyzed by nBu4NI using TBHP as oxidant from simple substrates, aryl methyl ketones and dialkylformamides.

Graphical abstract: nBu4NI-catalyzed direct synthesis of α-ketoamides from aryl methyl ketones with dialkylformamides in water using TBHP as oxidant

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Publication details

The article was received on 22 Jul 2012, accepted on 22 Aug 2012 and first published on 23 Aug 2012


Article type: Communication
DOI: 10.1039/C2CC35279F
Citation: Chem. Commun., 2012,48, 10117-10119
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    nBu4NI-catalyzed direct synthesis of α-ketoamides from aryl methyl ketones with dialkylformamides in water using TBHP as oxidant

    W. Mai, H. Wang, Z. Li, J. Yuan, Y. Xiao, L. Yang, P. Mao and L. Qu, Chem. Commun., 2012, 48, 10117
    DOI: 10.1039/C2CC35279F

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