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Issue 84, 2012
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Transmetallation between Metal-Only Lewis Pairs: a new rhodium alane complex

Jürgen Bauer,a  Holger Braunschweig*a  and  Krzysztof Radackia 
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* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, D-97074 Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de
Fax: +49 931 31 84623
Tel: +49 931 31 85260

Abstract

In this communication, synthesis of a rhodium alane Lewis adduct, [Cp(Me3P)2Rh→AlCl3], is reported. Given that direct synthesis using aluminium trichloride failed, a convenient transmetallation reaction was applied. The new MOLP was analysed by single crystal X-ray diffraction, multinuclear NMR spectroscopy and density functional theory calculations.

Graphical abstract: Transmetallation between Metal-Only Lewis Pairs: a new rhodium alane complex

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Publication details

The article was received on 20 Jul 2012, accepted on 30 Aug 2012 and first published on 06 Sep 2012


Article type: Communication
DOI: 10.1039/C2CC35248F
Citation: Chem. Commun., 2012,48, 10407-10409
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    Transmetallation between Metal-Only Lewis Pairs: a new rhodium alane complex

    J. Bauer, H. Braunschweig and K. Radacki, Chem. Commun., 2012, 48, 10407
    DOI: 10.1039/C2CC35248F

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