Transmetallation between Metal-Only Lewis Pairs: a new rhodium alane complex

Jürgen Bauer; Holger Braunschweig; Krzysztof Radacki

doi:10.1039/C2CC35248F

Transmetallation between Metal-Only Lewis Pairs: a new rhodium alane complex

Jürgen Bauer,^a Holger Braunschweig*^a and Krzysztof Radacki^a

* Corresponding authors

^a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, D-97074 Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de
Fax: +49 931 31 84623
Tel: +49 931 31 85260

Abstract

In this communication, synthesis of a rhodium alane Lewis adduct, [Cp(Me₃P)₂Rh→AlCl₃], is reported. Given that direct synthesis using aluminium trichloride failed, a convenient transmetallation reaction was applied. The new MOLP was analysed by single crystal X-ray diffraction, multinuclear NMR spectroscopy and density functional theory calculations.

Supplementary files

Publication details

The article was received on 20 Jul 2012, accepted on 30 Aug 2012 and first published on 06 Sep 2012

Article type: Communication

DOI: 10.1039/C2CC35248F

Citation: Chem. Commun., 2012,48, 10407-10409

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Transmetallation between Metal-Only Lewis Pairs: a new rhodium alane complex

J. Bauer, H. Braunschweig and K. Radacki, Chem. Commun., 2012, 48, 10407
DOI: 10.1039/C2CC35248F
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Chemical Communications

Transmetallation between Metal-Only Lewis Pairs: a new rhodium alane complex

Abstract

Supplementary files

Publication details

Transmetallation between Metal-Only Lewis Pairs: a new rhodium alane complex

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