In this communication, synthesis of a rhodium alane Lewis adduct, [Cp(Me3P)2Rh→AlCl3], is reported. Given that direct synthesis using
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Transmetallation between Metal-Only Lewis Pairs: a new rhodium alane complex
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Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, D-97074 Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de;
Fax: +49 931 31 84623 ;
Tel: +49 931 31 85260
E-mail: h.braunschweig@mail.uni-wuerzburg.de;
Fax: +49 931 31 84623 ;
Tel: +49 931 31 85260
Chem. Commun., 2012,48, 10407-10409
DOI: 10.1039/C2CC35248F
Received 20 Jul 2012, Accepted 30 Aug 2012
First published online 06 Sep 2012
Chemical Communications
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